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ï»żLast updated Save as PDF Page ID161838 Learning Objectives Describe the locations, charges, and masses of the three main subatomic particles. Determine the number of protons and electrons in an atom. Define atomic mass unit amu. Dalton's Atomic Theory explained a lot about matter, chemicals, and chemical reactions. Nevertheless, it was not entirely accurate, because contrary to what Dalton believed, atoms can, in fact, be broken apart into smaller subunits or subatomic particles. We have been talking about the electron in great detail, but there are two other particles of interest to us protons and neutrons. We already learned that J. J. Thomson discovered a negatively charged particle, called the electron. Rutherford proposed that these electrons orbit a positive nucleus. In subsequent experiments, he found that there is a smaller positively charged particle in the nucleus, called a proton. There is also a third subatomic particle, known as a neutron. Electrons Electrons are one of three main types of particles that make up atoms. Unlike protons and neutrons, which consist of smaller, simpler particles, electrons are fundamental particles that do not consist of smaller particles. They are a type of fundamental particle called leptons. All leptons have an electric charge of \-1\ or \0\. Electrons are extremely small. The mass of an electron is only about 1/2000 the mass of a proton or neutron, so electrons contribute virtually nothing to the total mass of an atom. Electrons have an electric charge of \-1\, which is equal but opposite to the charge of a proton, which is \+1\. All atoms have the same number of electrons as protons, so the positive and negative charges "cancel out", making atoms electrically neutral. Unlike protons and neutrons, which are located inside the nucleus at the center of the atom, electrons are found outside the nucleus. Because opposite electric charges attract one another, negative electrons are attracted to the positive nucleus. This force of attraction keeps electrons constantly moving through the otherwise empty space around the nucleus. The figure below is a common way to represent the structure of an atom. It shows the electron as a particle orbiting the nucleus, similar to the way that planets orbit the sun. However, this is an incorrect perspective, as quantum mechanics demonstrates that electrons are more complicated. Figure \\PageIndex{1}\ Electrons are much smaller than protons or neutrons. If an electron was the mass of a penny, a proton or a neutron would have the mass of a large bowling ball! Protons A proton is one of three main particles that make up the atom. Protons are found in the nucleus of the atom. This is a tiny, dense region at the center of the atom. Protons have a positive electrical charge of one \\left +1 \right\ and a mass of 1 atomic mass unit \\left \text{amu} \right\, which is about \ \times 10^{-27}\ kilograms. Together with neutrons, they make up virtually all of the mass of an atom. Neutrons Atoms of all elementsâexcept for most atoms of hydrogenâhave neutrons in their nucleus. Unlike protons and electrons, which are electrically charged, neutrons have no chargeâthey are electrically neutral. That's why the neutrons in the diagram above are labeled \n^0\. The zero stands for "zero charge". The mass of a neutron is slightly greater than the mass of a proton, which is 1 atomic mass unit \\left \text{amu} \right\. An atomic mass unit equals about \ \times 10^{-27}\ kilograms. A neutron also has about the same diameter as a proton, or \ \times 10^{-15}\ meters. As you might have already guessed from its name, the neutron is neutral. In other words, it has no charge whatsoever and is therefore neither attracted to nor repelled from other objects. Neutrons are in every atom with one exception, and they are bound together with other neutrons and protons in the atomic nucleus. Before we move on, we must discuss how the different types of subatomic particles interact with each other. When it comes to neutrons, the answer is obvious. Since neutrons are neither attracted to nor repelled from objects, they don't really interact with protons or electrons beyond being bound into the nucleus with the protons. Even though electrons, protons, and neutrons are all types of subatomic particles, they are not all the same size. When you compare the masses of electrons, protons, and neutrons, what you find is that electrons have an extremely small mass, compared to either protons or neutrons. On the other hand, the masses of protons and neutrons are fairly similar, although technically, the mass of a neutron is slightly larger than the mass of a proton. Because protons and neutrons are so much more massive than electrons, almost all of the mass of any atom comes from the nucleus, which contains all of the neutrons and protons. Table \\PageIndex{1}\ Properties of Subatomic Particles Particle Symbol Mass amu Relative Mass proton = 1 Relative Charge Location proton p+ 1 1 +1 inside the nucleus electron eâ Ă 10â4 â1 outside the nucleus neutron n0 1 1 0 inside the nucleus Table \\PageIndex{1}\ gives the properties and locations of electrons, protons, and neutrons. The third column shows the masses of the three subatomic particles in "atomic mass units." An atomic mass unit \\text{amu}\ is defined as one-twelfth of the mass of a carbon-12 atom. Atomic mass units \\text{amu}\ are useful, because, as you can see, the mass of a proton and the mass of a neutron are almost exactly \1\ in this unit system. Negative and positive charges of equal magnitude cancel each other out. This means that the negative charge on an electron perfectly balances the positive charge on the proton. In other words, a neutral atom must have exactly one electron for every proton. If a neutral atom has 1 proton, it must have 1 electron. If a neutral atom has 2 protons, it must have 2 electrons. If a neutral atom has 10 protons, it must have 10 electrons. You get the idea. In order to be neutral, an atom must have the same number of electrons and protons. Summary Electrons are a type of subatomic particle with a negative charge. Protons are a type of subatomic particle with a positive charge. Protons are bound together in an atom's nucleus as a result of the strong nuclear force. Neutrons are a type of subatomic particle with no charge they are neutral. Like protons, neutrons are bound into the atom's nucleus as a result of the strong nuclear force. Protons and neutrons have approximately the same mass, but they are both much more massive than electrons approximately 2,000 times as massive as an electron. The positive charge on a proton is equal in magnitude to the negative charge on an electron. As a result, a neutral atom must have an equal number of protons and electrons. The atomic mass unit amu is a unit of mass equal to one-twelfth the mass of a carbon-12 atom AnalisisElectron Beam Profile Constancy pada Pesawat Linac. Edi Guritna 1), Giner Maslebu 1,*), Nur Aji Wibowo 1), Muham mad Hidayatullah 2) 1) Program Studi Fisika dan Pendidikan Fisika Fundamental properties of atoms including atomic number and atomic mass. The atomic number is the number of protons in an atom, and isotopes have the same atomic number but differ in the number of pops up fairly often in the news. For instance, you might have read about it in discussions of nuclear energy, the Fukushima reactor tragedy, or the development of nuclear weapons. It also shows up in popular culture many superheroesâ origin stories involve radiation exposure, for instanceâor, in the case of Spider-Man, a bite from a radioactive spider. But what exactly does it mean for something to be radioactive?Radioactivity is actually a property of an atom. Radioactive atoms have unstable nuclei, and they will eventually release subatomic particles to become more stable, giving off energyâradiationâin the process. Often, elements come in both radioactive and nonradioactive versions that differ in the number of neutrons they contain. These different versions of elements are called isotopes, and small quantities of radioactive isotopes often occur in nature. For instance, a small amount of carbon exists in the atmosphere as radioactive carbon-14, and the amount of carbon-14 found in fossils allows paleontologists to determine their age. In this article, weâll look in more detail at the subatomic particles that different atoms contain as well as what makes an isotope number, atomic mass, and relative atomic massAtoms of each element contain a characteristic number of protons. In fact, the number of protons determines what atom we are looking at all atoms with six protons are carbon atoms; the number of protons in an atom is called the atomic number. In contrast, the number of neutrons for a given element can vary. Forms of the same atom that differ only in their number of neutrons are called isotopes. Together, the number of protons and the number of neutrons determine an elementâs mass number mass number = protons + neutrons. If you want to calculate how many neutrons an atom has, you can simply subtract the number of protons, or atomic number, from the mass property closely related to an atomâs mass number is its atomic mass. The atomic mass of a single atom is simply its total mass and is typically expressed in atomic mass units or amu. By definition, an atom of carbon with six neutrons, carbon-12, has an atomic mass of 12 amu. Other atoms donât generally have round-number atomic masses for reasons that are a little beyond the scope of this article. In general, though, an atom's atomic mass will be very close to its mass number, but will have some deviation in the decimal an elementâs isotopes have different atomic masses, scientists may also determine the relative atomic massâsometimes called the atomic weightâfor an element. The relative atomic mass is an average of the atomic masses of all the different isotopes in a sample, with each isotope's contribution to the average determined by how big a fraction of the sample it makes up. The relative atomic masses given in periodic table entriesâlike the one for hydrogen, belowâare calculated for all the naturally occurring isotopes of each element, weighted by the abundance of those isotopes on earth. Extraterrestrial objects, like asteroids or meteors, might have very different isotope and radioactive decayAs mentioned above, isotopes are different forms of an element that have the same number of protons but different numbers of neutrons. Many elementsâsuch as carbon, potassium, and uraniumâhave multiple naturally occurring isotopes. A neutral atom of Carbon-12 contains six protons, six neutrons, and six electrons; therefore, it has a mass number of 12 six protons plus six neutrons. Neutral carbon-14 contains six protons, eight neutrons, and six electrons; its mass number is 14 six protons plus eight neutrons. These two alternate forms of carbon are isotopes are stable, but others can emit, or kick out, subatomic particles to reach a more stable, lower-energy, configuration. Such isotopes are called radioisotopes, and the process in which they release particles and energy is known as decay. Radioactive decay can cause a change in the number of protons in the nucleus; when this happens, the identity of the atom changes carbon-14 decaying to nitrogen-14.Radioactive decay is a random but exponential process, and an isotopeâs half-life is the period over which half of the material will decay to a different, relatively stable product. The ratio of the original isotope to its decay product and to stable isotopes changes in a predictable way; this predictability allows the relative abundance of the isotope to be used as a clock that measures the time from the incorporation of the isotope into a fossil to the example, carbon is normally present in the atmosphere in the form of gases like carbon dioxide, and it exists in three isotopic forms carbon-12 and carbon-13, which are stable, and carbon-14, which is radioactive. These forms of carbon are found in the atmosphere in relatively constant proportions, with carbon-12 as the major form at about 99%, carbon-13 as a minor form at about 1%, and carbon-14 present only in tiny amountsstart superscript, 1, end superscript. As plants pull carbon dioxide from the air to make sugars, the relative amount of carbon-14 in their tissues will be equal to the concentration of carbon-14 in the atmosphere. As animals eat the plants, or eat other animals that ate plants, the concentrations of carbon-14 in their bodies will also match the atmospheric concentration. When an organism dies, it stops taking in carbon-14, so the ratio of carbon-14 to carbon-12 in its remains, such as fossilized bones, will decline as carbon-14 decays gradually to nitrogen-14squared. After a half-life of approximately 5,730 years, half of the carbon-14 that was initially present will have been converted to nitrogen-14. This property can be used to date formerly living objects such as old bones or wood. By comparing the ratio of carbon-14 to carbon-12 concentrations in an object to the same ratio in the atmosphere, equivalent to the starting concentration for the object, the fraction of the isotope that has not yet decayed can be determined. On the basis of this fraction, the age of the material can be calculated with accuracy if it is not much older than about 50,000 years. Other elements have isotopes with different half lives, and can thus be used to measure age on different timescales. For example, potassium-40 has a half-life of billion years, and uranium-235 has a half-life of about 700 million years and has been used to measure the age of moon rockssquared. Andaboleh menentukan jumlah elektron dalam ion jika anda tahu cajnya. Kation membawa caj positif dan mempunyai lebih banyak proton daripada elektron. Anion membawa caj negatif dan mempunyai lebih banyak elektron daripada proton. Neutrons tidak mempunyai caj elektrik bersih, jadi bilangan neutron tidak penting dalam pengiraan.A= 50 + 62 = 112 03) (Covest-2002) Istopos radiativos de iodo so utilizados no diagnstico e tratamento de problemas da tireide, e so, em geral, ministrados na forma de sais de iodeto. O nmero de prtons, nutrons e eltrons no istopo 131 131 do iodeto 53 I so, respectivamente: a) 53, 78 e 52. b) 53, 78 e 54. c) 53, 131 e 53. d) 131, 53 e 131.
Last updated Save as PDF Page ID369176 Learning Objectives Describe the locations, charges, and masses of the three main subatomic particles. Determine the number of protons and electrons in an atom. Write and interpret symbols that depict the atomic number, mass number, and charge of an atom or ion. Define the atomic mass unit and average atomic mass Dalton's Atomic Theory explained a lot about matter, chemicals, and chemical reactions. Nevertheless, it was not entirely accurate, because contrary to what Dalton believed, atoms can, in fact, be broken apart into smaller subunits or subatomic particles. We have been talking about the electron in great detail, but there are two other particles of interest to us protons and neutrons. We already learned that J. J. Thomson discovered a negatively charged particle, called the electron. Rutherford proposed that these electrons orbit a positive nucleus. In subsequent experiments, he found that there is a smaller positively charged particle in the nucleus, called a proton. There is also a third subatomic particle, known as a neutron. Electrons Electrons are one of three main types of particles that make up atoms. Unlike protons and neutrons, which consist of smaller, simpler particles, electrons are fundamental particles that do not consist of smaller particles. They are a type of fundamental particle called leptons. All leptons have an electric charge of \-1\ or \0\. Electrons are extremely small. The mass of an electron is only about 1/2000 the mass of a proton or neutron, so electrons contribute virtually nothing to the total mass of an atom. Electrons have an electric charge of \-1\, which is equal but opposite to the charge of a proton, which is \+1\. All atoms have the same number of electrons as protons, so the positive and negative charges "cancel out", making atoms electrically neutral. Unlike protons and neutrons, which are located inside the nucleus at the center of the atom, electrons are found outside the nucleus. Because opposite electric charges attract one another, negative electrons are attracted to the positive nucleus. This force of attraction keeps electrons constantly moving through the otherwise empty space around the nucleus. The figure below is a common way to represent the structure of an atom. It shows the electron as a particle orbiting the nucleus, similar to the way that planets orbit the sun. However, this is an incorrect perspective, as quantum mechanics demonstrates that electrons are more complicated. Figure \\PageIndex{1}\ Electrons are much smaller than protons or neutrons. If an electron was the mass of a penny, a proton or a neutron would have the mass of a large bowling ball! Protons A proton is one of three main particles that make up the atom. Protons are found in the nucleus of the atom. This is a tiny, dense region at the center of the atom. Protons have a positive electrical charge of one \\left +1 \right\ and a mass of 1 atomic mass unit \\left \text{amu} \right\, which is about \ \times 10^{-27}\ kilograms. Together with neutrons, they make up virtually all of the mass of an atom. Neutrons Atoms of all elementsâexcept for most atoms of hydrogenâhave neutrons in their nucleus. Unlike protons and electrons, which are electrically charged, neutrons have no chargeâthey are electrically neutral. That's why the neutrons in the diagram above are labeled \n^0\. The zero stands for "zero charge". The mass of a neutron is slightly greater than the mass of a proton, which is 1 atomic mass unit \\left \text{amu} \right\. An atomic mass unit equals about \ \times 10^{-27}\ kilograms. A neutron also has about the same diameter as a proton, or \ \times 10^{-15}\ meters. As you might have already guessed from its name, the neutron is neutral. In other words, it has no charge whatsoever and is therefore neither attracted to nor repelled from other objects. Neutrons are in every atom with one exception, and they are bound together with other neutrons and protons in the atomic nucleus. Before we move on, we must discuss how the different types of subatomic particles interact with each other. When it comes to neutrons, the answer is obvious. Since neutrons are neither attracted to nor repelled from objects, they don't really interact with protons or electrons beyond being bound into the nucleus with the protons. Even though electrons, protons, and neutrons are all types of subatomic particles, they are not all the same size. When you compare the masses of electrons, protons, and neutrons, what you find is that electrons have an extremely small mass, compared to either protons or neutrons. On the other hand, the masses of protons and neutrons are fairly similar, although technically, the mass of a neutron is slightly larger than the mass of a proton. Because protons and neutrons are so much more massive than electrons, almost all of the mass of any atom comes from the nucleus, which contains all of the neutrons and protons. Table \\PageIndex{1}\ Properties of Subatomic Particles Particle Symbol Mass amu Relative Mass proton = 1 Relative Charge Location proton p+ 1 1 +1 inside the nucleus electron eâ Ă 10â4 â1 outside the nucleus neutron n0 1 1 0 inside the nucleus Table \\PageIndex{1}\ gives the properties and locations of electrons, protons, and neutrons. The third column shows the masses of the three subatomic particles in "atomic mass units." An atomic mass unit \\text{amu}\ is defined as one-twelfth of the mass of a carbon-12 atom. Atomic mass units \\text{amu}\ are useful, because, as you can see, the mass of a proton and the mass of a neutron are almost exactly \1\ in this unit system. Negative and positive charges of equal magnitude cancel each other out. This means that the negative charge on an electron perfectly balances the positive charge on the proton. In other words, a neutral atom must have exactly one electron for every proton. If a neutral atom has 1 proton, it must have 1 electron. If a neutral atom has 2 protons, it must have 2 electrons. If a neutral atom has 10 protons, it must have 10 electrons. You get the idea. In order to be neutral, an atom must have the same number of electrons and protons. Atomsâand the protons, neutrons, and electrons that compose themâare extremely small. For example, a carbon atom weighs less than 2 \\times\ 10â23 g, and an electron has a charge of less than 2 \\times\ 10â19 C coulomb. When describing the properties of tiny objects such as atoms, we use appropriately small units of measure, such as the atomic mass unit amu and the fundamental unit of charge e. The amu was originally defined based on hydrogen, the lightest element, then later in terms of oxygen. Since 1961, it has been defined with regard to the most abundant isotope of carbon, atoms of which are assigned masses of exactly 12 amu. This isotope is known as âcarbon-12â as will be discussed later in this module. Thus, one amu is exactly \1/12\ of the mass of one carbon-12 atom 1 amu = \\times\ 10â24 g. The Dalton Da and the unified atomic mass unit u are alternative units that are equivalent to the amu. Atomic Number The number of protons in the nucleus of an atom is its atomic number \Z\. This is the defining trait of an element Its value determines the identity of the atom. For example, any atom that contains six protons is the element carbon and has the atomic number 6, regardless of how many neutrons or electrons it may have. A neutral atom must contain the same number of positive and negative charges, so the number of protons equals the number of electrons. Therefore, the atomic number also indicates the number of electrons in an atom. The total number of protons and neutrons in an atom is called its mass number A. The number of neutrons is therefore the difference between the mass number and the atomic number A â Z = number of neutrons. \[\begin{align*} \ce{atomic\ number\Z\ &= \number\ of\ protons\\ mass\ number\A\ &= \number\ of\ protons + number\ of\ neutrons\\ A-Z\ &= \number\ of\ neutrons} \end{align*} \nonumber \] Atoms are electrically neutral if they contain the same number of positively charged protons and negatively charged electrons. When the numbers of these subatomic particles are not equal, the atom is electrically charged and is called an ion. The charge of an atom is defined as follows Atomic charge = number of protons â number of electrons As will be discussed in more detail later in this chapter, atoms and molecules typically acquire charge by gaining or losing electrons. An atom that gains one or more electrons will exhibit a negative charge and is called an anion. Positively charged atoms called cations are formed when an atom loses one or more electrons. For example, a neutral sodium atom Z = 11 has 11 electrons. If this atom loses one electron, it will become a cation with a 1+ charge 11 â 10 = 1+. A neutral oxygen atom Z = 8 has eight electrons, and if it gains two electrons it will become an anion with a 2â charge 8 â 10 = 2â. Example \\PageIndex{1}\ Composition of an Atom Iodine is an essential trace element in our diet; it is needed to produce thyroid hormone. Insufficient iodine in the diet can lead to the development of a goiter, an enlargement of the thyroid gland Figure \\PageIndex{2}\. Figure \\PageIndex{2}\ a Insufficient iodine in the diet can cause an enlargement of the thyroid gland called a goiter. b The addition of small amounts of iodine to salt, which prevents the formation of goiters, has helped eliminate this concern in the US where salt consumption is high. credit a modification of work by âAlmaziâ/Wikimedia Commons; credit b modification of work by Mike Mozart The addition of small amounts of iodine to table salt iodized salt has essentially eliminated this health concern in the United States, but as much as 40% of the worldâs population is still at risk of iodine deficiency. The iodine atoms are added as anions, and each has a 1â charge and a mass number of 127. Determine the numbers of protons, neutrons, and electrons in one of these iodine anions. Solution The atomic number of iodine 53 tells us that a neutral iodine atom contains 53 protons in its nucleus and 53 electrons outside its nucleus. Because the sum of the numbers of protons and neutrons equals the mass number, 127, the number of neutrons is 74 127 â 53 = 74. Since the iodine is added as a 1â anion, the number of electrons is 54 [53 â 1â = 54]. Exercise \\PageIndex{1}\ An ion of platinum has a mass number of 195 and contains 74 electrons. How many protons and neutrons does it contain, and what is its charge? Answer 78 protons; 117 neutrons; charge is 4+ Chemical Symbols A chemical symbol is an abbreviation that we use to indicate an element or an atom of an element. For example, the symbol for mercury is Hg Figure \\PageIndex{3}\. We use the same symbol to indicate one atom of mercury microscopic domain or to label a container of many atoms of the element mercury macroscopic domain. Figure \\PageIndex{3}\ The symbol Hg represents the element mercury regardless of the amount; it could represent one atom of mercury or a large amount of mercury. from Wikipedia user Materialscientist. The symbols for several common elements and their atoms are listed in Table \\PageIndex{2}\. Some symbols are derived from the common name of the element; others are abbreviations of the name in another language. Symbols have one or two letters, for example, H for hydrogen and Cl for chlorine. To avoid confusion with other notations, only the first letter of a symbol is capitalized. For example, Co is the symbol for the element cobalt, but CO is the notation for the compound carbon monoxide, which contains atoms of the elements carbon C and oxygen O. All known elements and their symbols are in the periodic table. Table \\PageIndex{2}\ Some Common Elements and Their Symbols Element Symbol Element Symbol aluminum Al iron Fe from ferrum bromine Br lead Pb from plumbum calcium Ca magnesium Mg carbon C mercury Hg from hydrargyrum chlorine Cl nitrogen N chromium Cr oxygen O cobalt Co potassium K from kalium copper Cu from cuprum silicon Si fluorine F silver Ag from argentum gold Au from aurum sodium Na from natrium helium He sulfur S hydrogen H tin Sn from stannum iodine I zinc Zn Traditionally, the discoverer or discoverers of a new element names the element. However, until the name is recognized by the International Union of Pure and Applied Chemistry IUPAC, the recommended name of the new element is based on the Latin words for its atomic number. For example, element 106 was called unnilhexium Unh, element 107 was called unnilseptium Uns, and element 108 was called unniloctium Uno for several years. These elements are now named after scientists or locations; for example, element 106 is now known as seaborgium Sg in honor of Glenn Seaborg, a Nobel Prize winner who was active in the discovery of several heavy elements. Isotopes The symbol for a specific isotope of any element is written by placing the mass number as a superscript to the left of the element symbol Figure \\PageIndex{4}\. The atomic number is sometimes written as a subscript preceding the symbol, but since this number defines the elementâs identity, as does its symbol, it is often omitted. For example, magnesium exists as a mixture of three isotopes, each with an atomic number of 12 and with mass numbers of 24, 25, and 26, respectively. These isotopes can be identified as 24Mg, 25Mg, and 26Mg. These isotope symbols are read as âelement, mass numberâ and can be symbolized consistent with this reading. For instance, 24Mg is read as âmagnesium 24,â and can be written as âmagnesium-24â or âMg-24.â 25Mg is read as âmagnesium 25,â and can be written as âmagnesium-25â or âMg-25.â All magnesium atoms have 12 protons in their nucleus. They differ only because a 24Mg atom has 12 neutrons in its nucleus, a 25Mg atom has 13 neutrons, and a 26Mg has 14 neutrons. Figure \\PageIndex{4}\ The symbol for an atom indicates the element via its usual two-letter symbol, the mass number as a left superscript, the atomic number as a left subscript sometimes omitted, and the charge as a right superscript. Information about the naturally occurring isotopes of elements with atomic numbers 1 through 10 is given in Table \\PageIndex{2}\. Note that in addition to standard names and symbols, the isotopes of hydrogen are often referred to using common names and accompanying symbols. Hydrogen-2, symbolized 2H, is also called deuterium and sometimes symbolized D. Hydrogen-3, symbolized 3H, is also called tritium and sometimes symbolized T. Table \\PageIndex{2}\ Nuclear Compositions of Atoms of the Very Light Elements Element Symbol Atomic Number Number of Protons Number of Neutrons Mass amu % Natural Abundance hydrogen \\ce{^1_1H}\ protium 1 1 0 \\ce{^2_1H}\ deuterium 1 1 1 \\ce{^3_1H}\ tritium 1 1 2 â trace helium \\ce{^3_2He}\ 2 2 1 \\ce{^4_2He}\ 2 2 2 100 lithium \\ce{^6_3Li}\ 3 3 3 \\ce{^7_3Li}\ 3 3 4 beryllium \\ce{^9_4Be}\ 4 4 5 100 boron \\ce{^{10}_5B}\ 5 5 5 \\ce{^{11}_5B}\ 5 5 6 carbon \\ce{^{12}_6C}\ 6 6 6 \\ce{^{13}_6C}\ 6 6 7 \\ce{^{14}_6C}\ 6 6 8 â trace nitrogen \\ce{^{14}_7N}\ 7 7 7 \\ce{^{15}_7N}\ 7 7 8 oxygen \\ce{^{16}_8O}\ 8 8 8 \\ce{^{17}_8O}\ 8 8 9 \\ce{^{18}_8O}\ 8 8 10 fluorine \\ce{^{19}_9F}\ 9 9 10 100 neon \\ce{^{20}_{10}Ne}\ 10 10 10 \\ce{^{21}_{10}Ne}\ 10 10 11 \\ce{^{22}_{10}Ne}\ 10 10 12 Atomic Mass Because each proton and each neutron contribute approximately one amu to the mass of an atom, and each electron contributes far less, the atomic mass of a single atom is approximately equal to its mass number a whole number. However, the average masses of atoms of most elements are not whole numbers because most elements exist naturally as mixtures of two or more isotopes. The mass of an element shown in a periodic table or listed in a table of atomic masses is a weighted, average mass of all the isotopes present in a naturally occurring sample of that element. This is equal to the sum of each individual isotopeâs mass multiplied by its fractional abundance. \[\mathrm{average\ mass}=\sum_{i}\mathrm{fractional\ abundance\times isotopic\ mass}_i \nonumber \] For example, the element boron is composed of two isotopes About of all boron atoms are 10B with a mass of amu, and the remaining are 11B with a mass of amu. The average atomic mass for boron is calculated to be \[\begin{align*} \textrm{boron average mass} &=\mathrm{ amu+ amu}\\ &=\mathrm{ amu+ amu}\\ &=\mathrm{ amu} \end{align*} \nonumber \] It is important to understand that no single boron atom weighs exactly amu; amu is the average mass of all boron atoms, and individual boron atoms weigh either approximately 10 amu or 11 amu. Example \\PageIndex{2}\ Calculation of Average Atomic Mass A meteorite found in central Indiana contains traces of the noble gas neon picked up from the solar wind during the meteoriteâs trip through the solar system. Analysis of a sample of the gas showed that it consisted of 20Ne mass amu, 21Ne mass amu, and 22Ne mass amu. What is the average mass of the neon in the solar wind? Solution \[\begin{align*} \mathrm{average\ mass} &=\mathrm{ amu+ amu+ amu}\\ &=\mathrm{ &=\mathrm{ amu} \end{align*} \nonumber \] The average mass of a neon atom in the solar wind is amu. The average mass of a terrestrial neon atom is amu. This result demonstrates that we may find slight differences in the natural abundance of isotopes, depending on their origin. Exercise \\PageIndex{2}\ A sample of magnesium is found to contain of 24Mg atoms mass amu, of 25Mg atoms mass amu, and of 26Mg atoms mass amu. Calculate the average mass of a Mg atom. Answer amu We can also do variations of this type of calculation, as shown in the next example. Example \\PageIndex{3}\ Calculation of Percent Abundance Naturally occurring chlorine consists of 35Cl mass amu and 37Cl mass amu, with an average mass of amu. What is the percent composition of Cl in terms of these two isotopes? Solution The average mass of chlorine is the fraction that is 35Cl times the mass of 35Cl plus the fraction that is 37Cl times the mass of 37Cl. \[\mathrm{average\ mass=fraction\ of\ ^{35}Cl\times mass\ of\ ^{35}Cl+fraction\ of\ ^{37}Cl\times mass\ of\ ^{37}Cl} \nonumber \] If we let x represent the fraction that is 35Cl, then the fraction that is 37Cl is represented by â x. The fraction that is 35Cl + the fraction that is 37Cl must add up to 1, so the fraction of 37Cl must equal â the fraction of 35Cl. Substituting this into the average mass equation, we have \[\begin{align*} \mathrm{ amu} &=x\times \ce{amu}+[ \ce{amu}]\\ &= &= x&=\dfrac{ \end{align*} \nonumber \] So solving yields x = which means that â = Therefore, chlorine consists of 35Cl and 37Cl. Exercise \\PageIndex{3}\ Naturally occurring copper consists of 63Cu mass amu and 65Cu mass amu, with an average mass of amu. What is the percent composition of Cu in terms of these two isotopes? Answer Cu-63 and Cu-65 Figure \\PageIndex{5}\ Analysis of zirconium in a mass spectrometer produces a mass spectrum with peaks showing the different isotopes of Zr. The occurrence and natural abundances of isotopes can be experimentally determined using an instrument called a mass spectrometer. Mass spectrometry MS is widely used in chemistry, forensics, medicine, environmental science, and many other fields to analyze and help identify the substances in a sample of material. In a typical mass spectrometer Figure \\PageIndex{5}\, the sample is vaporized and exposed to a high-energy electron beam that causes the sampleâs atoms or molecules to become electrically charged, typically by losing one or more electrons. These cations then pass through a variable electric or magnetic field that deflects each cationâs path to an extent that depends on both its mass and charge similar to how the path of a large steel ball bearing rolling past a magnet is deflected to a lesser extent that that of a small steel BB. The ions are detected, and a plot of the relative number of ions generated versus their mass-to-charge ratios a mass spectrum is made. The height of each vertical feature or peak in a mass spectrum is proportional to the fraction of cations with the specified mass-to-charge ratio. Since its initial use during the development of modern atomic theory, MS has evolved to become a powerful tool for chemical analysis in a wide range of applications. Video \\PageIndex{1}\ Watch this video from the Royal Society for Chemistry for a brief description of the rudiments of mass spectrometry. Summary An atom consists of a small, positively charged nucleus surrounded by electrons. The nucleus contains protons and neutrons; its diameter is about 100,000 times smaller than that of the atom. The mass of one atom is usually expressed in atomic mass units amu, which is referred to as the atomic mass. An amu is defined as exactly \1/12\ of the mass of a carbon-12 atom and is equal to \\times\ 10â24 g. Protons are relatively heavy particles with a charge of 1+ and a mass of amu. Neutrons are relatively heavy particles with no charge and a mass of amu. Electrons are light particles with a charge of 1â and a mass of amu. The number of protons in the nucleus is called the atomic number Z and is the property that defines an atomâs elemental identity. The sum of the numbers of protons and neutrons in the nucleus is called the mass number and, expressed in amu, is approximately equal to the mass of the atom. An atom is neutral when it contains equal numbers of electrons and protons. Isotopes of an element are atoms with the same atomic number but different mass numbers; isotopes of an element, therefore, differ from each other only in the number of neutrons within the nucleus. When a naturally occurring element is composed of several isotopes, the atomic mass of the element represents the average of the masses of the isotopes involved. A chemical symbol identifies the atoms in a substance using symbols, which are one-, two-, or three-letter abbreviations for the atoms. Key Equations \\mathrm{average\ mass}=\sum_{i}\mathrm{fractional\ abundance \times isotopic\ mass}_i\ Glossary anion negatively charged atom or molecule contains more electrons than protons atomic mass average mass of atoms of an element, expressed in amu atomic mass unit amu also, unified atomic mass unit, u, or Dalton, Da unit of mass equal to \\dfrac{1}{12}\ of the mass of a 12C atom atomic number Z number of protons in the nucleus of an atom cation positively charged atom or molecule contains fewer electrons than protons chemical symbol one-, two-, or three-letter abbreviation used to represent an element or its atoms Dalton Da alternative unit equivalent to the atomic mass unit fundamental unit of charge also called the elementary charge equals the magnitude of the charge of an electron e with e = \\times\ 10â19 C ion electrically charged atom or molecule contains unequal numbers of protons and electrons mass number A sum of the numbers of neutrons and protons in the nucleus of an atom unified atomic mass unit u alternative unit equivalent to the atomic mass unit Jumlahelektron pada ion kalium adalah . A. 16 B. 17 C. 18 D. 19 E. 20 3. Lambang suatu unsur 18 X 40 dapat disimpulkan bahwa pada satu atom unsur X mempunyai . A. 18 neutron dan 18 proton B. 22 neutron dan 22 proton C. 40 proton dan 18 elektron D. 18 proton dan 22 neutron E. 18 neutron, 22 proton, dan 22 elektron 4. Kelemahan teori atom